Synthesis and application of a new polystyrene-supported ruthenium carbene catalyst for alkene metathesis

Piotr Nieczypor; Wlodzimierz Buchowicz; Wim J.N. Meester; Floris P.J.T. Rutjes; Johannes C. Mol

doi:10.1016/S0040-4039(01)01460-5

Synthesis and application of a new polystyrene-supported ruthenium carbene catalyst for alkene metathesis

Piotr Nieczypor, Wlodzimierz Buchowicz, Wim J.N. Meester, Floris P.J.T. Rutjes, Johannes C. Mol

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

A ruthenium carbene complex was permanently immobilised on a functionalised polystyrene resin by reaction with a supported silver salt of a carboxylic acid. The catalyst thus prepared was active in the self-metathesis of internal alkenes as well as in ring-closing metathesis. It was easily separated from the reaction products, which were almost free from ruthenium contamination, and also recycled.

Original language	English
Pages (from-to)	7103-7105
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	40
DOIs	https://doi.org/10.1016/S0040-4039(01)01460-5
State	Published - Oct 1 2001
Externally published	Yes

Keywords

Alkene metathesis
Carbene complexes
Polystyrene-supported catalyst
Ruthenium

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10.1016/S0040-4039(01)01460-5

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title = "Synthesis and application of a new polystyrene-supported ruthenium carbene catalyst for alkene metathesis",

abstract = "A ruthenium carbene complex was permanently immobilised on a functionalised polystyrene resin by reaction with a supported silver salt of a carboxylic acid. The catalyst thus prepared was active in the self-metathesis of internal alkenes as well as in ring-closing metathesis. It was easily separated from the reaction products, which were almost free from ruthenium contamination, and also recycled.",

keywords = "Alkene metathesis, Carbene complexes, Polystyrene-supported catalyst, Ruthenium",

author = "Piotr Nieczypor and Wlodzimierz Buchowicz and Meester, {Wim J.N.} and Rutjes, {Floris P.J.T.} and Mol, {Johannes C.}",

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AU - Nieczypor, Piotr

AU - Buchowicz, Wlodzimierz

AU - Meester, Wim J.N.

AU - Rutjes, Floris P.J.T.

AU - Mol, Johannes C.

PY - 2001/10/1

Y1 - 2001/10/1

N2 - A ruthenium carbene complex was permanently immobilised on a functionalised polystyrene resin by reaction with a supported silver salt of a carboxylic acid. The catalyst thus prepared was active in the self-metathesis of internal alkenes as well as in ring-closing metathesis. It was easily separated from the reaction products, which were almost free from ruthenium contamination, and also recycled.

AB - A ruthenium carbene complex was permanently immobilised on a functionalised polystyrene resin by reaction with a supported silver salt of a carboxylic acid. The catalyst thus prepared was active in the self-metathesis of internal alkenes as well as in ring-closing metathesis. It was easily separated from the reaction products, which were almost free from ruthenium contamination, and also recycled.

KW - Alkene metathesis

KW - Carbene complexes

KW - Polystyrene-supported catalyst

KW - Ruthenium

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U2 - 10.1016/S0040-4039(01)01460-5

DO - 10.1016/S0040-4039(01)01460-5

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 40

ER -

Synthesis and application of a new polystyrene-supported ruthenium carbene catalyst for alkene metathesis

Abstract

Keywords

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