Reactions of tellurium chloride pentafluoride, TeF5Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF4)2·NR2Cl, where R = CH3, C2H51 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin ...

Joseph S. Thrasher; Matthew Clark; Peter A. Morken

doi:10.1016/S0022-1139(00)82779-7

Reactions of tellurium chloride pentafluoride, TeF₅Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF₄)₂·NR₂Cl, where R = CH₃, C₂H₅¹ 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin ...

Joseph S. Thrasher
, Matthew Clark
, Peter A. Morken

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Title full: Reactions of tellurium chloride pentafluoride, TeF₅Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF₄)₂·NR₂Cl, where R = CH₃, C₂H₅¹ 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin, G.D.R., August 1985; paper A-12, J. Fluorine Chem., 29 (1985) 34. Reactions of TeF₅Cl with the nitrogen nucleophiles LiN=C(CF₃)₂, [(CH₃)₃Si]₂NH, and (CH₃)₃SiNR₂, Where R = CH₃, C₂H₅, result in the reduction of the tellurium to Te(IV) and chlorination of the respective nucleophile. Analogous results are obtained in the reactions of TeF₅Cl with (CH₃)₃SiCN, C₆F₅Li, and C₆F₅SLi. In the case of (CH₃)₃SiNR₂, the new adducts (TeF₄)₂·NR₂Cl are obtained in high yield. These compounds have been identified through their infrared, ¹H, ¹⁹F, and ¹²⁵Te NMR, and mass spectra as well as by elemental analysis.

Original language	English
Pages (from-to)	235-243
Number of pages	9
Journal	Journal of Fluorine Chemistry
Volume	39
Issue number	2
DOIs	https://doi.org/10.1016/S0022-1139(00)82779-7
State	Published - Jan 1 1988
Externally published	Yes

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Thrasher, J. S., Clark, M., & Morken, P. A. (1988). Reactions of tellurium chloride pentafluoride, TeF₅Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF₄)₂·NR₂Cl, where R = CH₃, C₂H₅¹ 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin ... Journal of Fluorine Chemistry, 39(2), 235-243. https://doi.org/10.1016/S0022-1139(00)82779-7

Thrasher, Joseph S. ; Clark, Matthew ; Morken, Peter A. / Reactions of tellurium chloride pentafluoride, TeF₅Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF₄)₂·NR₂Cl, where R = CH₃, C₂H₅¹ 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin ... In: Journal of Fluorine Chemistry. 1988 ; Vol. 39, No. 2. pp. 235-243.

@article{065b073ac2834f41b51afa51b0dda951,

title = "Reactions of tellurium chloride pentafluoride, TeF5Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF4)2·NR2Cl, where R = CH3, C2H51 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin ...",

abstract = "Title full: Reactions of tellurium chloride pentafluoride, TeF5 Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF4)2·NR2Cl, where R = CH3, C2H51 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin, G.D.R., August 1985; paper A-12, J. Fluorine Chem., 29 (1985) 34. Reactions of TeF5Cl with the nitrogen nucleophiles LiN=C(CF3)2, [(CH3)3Si]2NH, and (CH3)3SiNR2, Where R = CH3, C2H5, result in the reduction of the tellurium to Te(IV) and chlorination of the respective nucleophile. Analogous results are obtained in the reactions of TeF5Cl with (CH3)3SiCN, C6F5Li, and C6F5SLi. In the case of (CH3)3SiNR2, the new adducts (TeF4)2·NR2Cl are obtained in high yield. These compounds have been identified through their infrared, 1H, 19F, and 125Te NMR, and mass spectra as well as by elemental analysis.",

author = "Thrasher, \{Joseph S.\} and Matthew Clark and Morken, \{Peter A.\}",

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doi = "10.1016/S0022-1139(00)82779-7",

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Thrasher, JS, Clark, M & Morken, PA 1988, 'Reactions of tellurium chloride pentafluoride, TeF₅Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF₄)₂·NR₂Cl, where R = CH₃, C₂H₅¹ 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin ...', Journal of Fluorine Chemistry, vol. 39, no. 2, pp. 235-243. https://doi.org/10.1016/S0022-1139(00)82779-7

Reactions of tellurium chloride pentafluoride, TeF₅Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF₄)₂·NR₂Cl, where R = CH₃, C₂H₅¹ 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin ... / Thrasher, Joseph S.; Clark, Matthew; Morken, Peter A.
In: Journal of Fluorine Chemistry, Vol. 39, No. 2, 01.01.1988, p. 235-243.

Research output: Contribution to journal › Article › peer-review

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T1 - Reactions of tellurium chloride pentafluoride, TeF5Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF4)2·NR2Cl, where R = CH3, C2H51 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin ...

AU - Thrasher, Joseph S.

AU - Clark, Matthew

AU - Morken, Peter A.

PY - 1988/1/1

Y1 - 1988/1/1

N2 - Title full: Reactions of tellurium chloride pentafluoride, TeF5 Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF4)2·NR2Cl, where R = CH3, C2H51 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin, G.D.R., August 1985; paper A-12, J. Fluorine Chem., 29 (1985) 34. Reactions of TeF5Cl with the nitrogen nucleophiles LiN=C(CF3)2, [(CH3)3Si]2NH, and (CH3)3SiNR2, Where R = CH3, C2H5, result in the reduction of the tellurium to Te(IV) and chlorination of the respective nucleophile. Analogous results are obtained in the reactions of TeF5Cl with (CH3)3SiCN, C6F5Li, and C6F5SLi. In the case of (CH3)3SiNR2, the new adducts (TeF4)2·NR2Cl are obtained in high yield. These compounds have been identified through their infrared, 1H, 19F, and 125Te NMR, and mass spectra as well as by elemental analysis.

AB - Title full: Reactions of tellurium chloride pentafluoride, TeF5 Cl, with nitrogen nucleophiles. Preparation and characterization of the adducts (TeF4)2·NR2Cl, where R = CH3, C2H51 1 Presented in part at the 11th International Symposium on Fluorine Chemistry, East Berlin, G.D.R., August 1985; paper A-12, J. Fluorine Chem., 29 (1985) 34. Reactions of TeF5Cl with the nitrogen nucleophiles LiN=C(CF3)2, [(CH3)3Si]2NH, and (CH3)3SiNR2, Where R = CH3, C2H5, result in the reduction of the tellurium to Te(IV) and chlorination of the respective nucleophile. Analogous results are obtained in the reactions of TeF5Cl with (CH3)3SiCN, C6F5Li, and C6F5SLi. In the case of (CH3)3SiNR2, the new adducts (TeF4)2·NR2Cl are obtained in high yield. These compounds have been identified through their infrared, 1H, 19F, and 125Te NMR, and mass spectra as well as by elemental analysis.

UR - https://www.scopus.com/pages/publications/50849146576

U2 - 10.1016/S0022-1139(00)82779-7

DO - 10.1016/S0022-1139(00)82779-7

M3 - Artículo

AN - SCOPUS:50849146576

SN - 0022-1139

VL - 39

SP - 235

EP - 243

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

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