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Effect of graphene oxide dosage on the thermal and rheological behavior of asphalt for tropical road conditions

  • Erick Mendoza
  • , Talia Tene
  • , Jorge Albuja-Sánchez
  • , Guisella Cuenca
  • , John Ramón
  • , David Anzules
  • , Cristian Vacacela Gomez
  • , Yolenny Cruz Salazar
  • , Lorenzo S. Caputi
  • , Salvatore Straface

    Research output: Contribution to journalArticlepeer-review

    Abstract

    This study investigates graphene oxide (GO) as a low-percent modifier for AC-30 asphalt used in tropical conditions. GO was added at 0.2, 0.4, and 0.6 wt% and tested through standard binder tests and RTFO short-term aging. Unaged binders with GO showed increased viscosity and hardness—viscosity rose by up to approximately 26%, penetration decreased by about 8%–13%, and the softening point rose slightly—indicating a stiffer initial matrix. During mixing at 135 °C–165 °C, both rotational and kinematic viscosities increased, with the highest gains near 0.4 wt%, suggesting a non-linear response to dosage. Under RTFO aging, GO-modified binders exhibited a higher viscosity aging index than the unmodified AC-30, indicating that GO enhances initial stiffness and does not compromise short-term oxidative hardening. Flash and fire points did not show systematic reductions at these dosages. Overall, sub-percent GO improves high-temperature rheology relevant for hot-climate pavements, but there is a trade-off between better early rutting resistance and potential stiffening with aging. Future research will include PAV/DSR testing and analysis of dispersion better to understand long-term behavior and processing at the plant level.

    Original languageEnglish
    Article number1691517
    JournalFrontiers in Chemistry
    Volume13
    DOIs
    StatePublished - 2025

    Keywords

    • asphalt
    • graphene oxide
    • hardness
    • resistance
    • viscosity

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